CH3411 UNIT PROCESSES IN ORGANIC SYNTHESIS SYLLABUS | ANNA UNIVERSITY BTECH PHARMACEUTICAL 8TH SEMESTER SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY 8TH SEMESTER B.TECH PHARMACEUTICAL DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
CH3411 UNIT PROCESSES IN ORGANIC SYNTHESIS
UNIT I SULFONATION AND SULFATION 12
Sulfating – Sulfonating agents – Applications – Chemical and physical factors in
sulfonation and sulfation – Thermodynamics mechanism – Kinetic considerations –
Industrial equipments and techniques – Sulfonation of benzene – Aniline.
UNIT II NITRATION 12
Nitrating agents – Aromatic nitration – Thermodynamics – Kinetics of nitration process –
Nitration of benzene – Toluene – Phenol – Glycerine – Naphthalene – Industrial
equipments for nitration – Preparation of m-dinitrobenzene – Chloro-nitro benzenes –
Continuous nitration process.
UNIT III AMINATION BY REDUCTION 12
Methods of reduction – Bechamp method – Reduction mechanism – Preparation of
aniline, p-phenylenediamine – Catalytic hydrogenation process – Catalyst involved in the
reduction process – Reduction mechanism – Manufacture of aniline using catalytic
reduction – Manufacture of p-aminophenol – Electrolytic reduction.
L T P C
0 0 3 2
L T P C
4 0 0 4
63
UNIT IV HALOGENATION 12
Halogenating agents – Thermodynamic and kinetic considerations – Chlorination of
methane – Ethane – Propane – Photohalogenation – Manufacture of allyl chloride –
Chloroacetic acid – Chloral hydrate – Ethylene chlorohydrin – Chloromethane – Vinyl
chloride.
UNIT V OXIDATION 12
Oxidation reactions – Oxidizing agents – Liquid phase and vapour phase oxidation with
air and oxygen – Catalysts used – Kinetics and thermodynamic consideration –
Manufacture of phthalic anhydride – Acetaldehyde – Acetic acid – Benzaldehyde –
Salicylic acid.
TOTAL: 60 PERIODS
TEXT BOOKS
1. Groggins, P.H., “Unit Processes in Organic Synthesis”, 5th Edition, McGraw Hill
Ltd., 1995.
2. Morison, R.T. and Boyd, R.N., “Organic Chemistry”, 6th Edition, Prentice Hall of
India (P) Ltd, 2006.
REFERENCES
1. Mukharjee, S. and Singh, S.P., “Reaction Mechanism in Organic Chemistry”, 3rd
Edition, Mc Millan India Ltd., 2000.
2. Jerry, M., “Advanced Organic Chemistry – Reactions, Mechanism and Structure”,
4th Edition, John-Wiley and Sons, 1992.
3. Bruckner, R., “Advanced Organic Chemistry- Reactions Mechanisms”, Academic
Press, 2002.
CH3411 UNIT PROCESSES IN ORGANIC SYNTHESIS
UNIT I SULFONATION AND SULFATION 12
Sulfating – Sulfonating agents – Applications – Chemical and physical factors in
sulfonation and sulfation – Thermodynamics mechanism – Kinetic considerations –
Industrial equipments and techniques – Sulfonation of benzene – Aniline.
UNIT II NITRATION 12
Nitrating agents – Aromatic nitration – Thermodynamics – Kinetics of nitration process –
Nitration of benzene – Toluene – Phenol – Glycerine – Naphthalene – Industrial
equipments for nitration – Preparation of m-dinitrobenzene – Chloro-nitro benzenes –
Continuous nitration process.
UNIT III AMINATION BY REDUCTION 12
Methods of reduction – Bechamp method – Reduction mechanism – Preparation of
aniline, p-phenylenediamine – Catalytic hydrogenation process – Catalyst involved in the
reduction process – Reduction mechanism – Manufacture of aniline using catalytic
reduction – Manufacture of p-aminophenol – Electrolytic reduction.
L T P C
0 0 3 2
L T P C
4 0 0 4
63
UNIT IV HALOGENATION 12
Halogenating agents – Thermodynamic and kinetic considerations – Chlorination of
methane – Ethane – Propane – Photohalogenation – Manufacture of allyl chloride –
Chloroacetic acid – Chloral hydrate – Ethylene chlorohydrin – Chloromethane – Vinyl
chloride.
UNIT V OXIDATION 12
Oxidation reactions – Oxidizing agents – Liquid phase and vapour phase oxidation with
air and oxygen – Catalysts used – Kinetics and thermodynamic consideration –
Manufacture of phthalic anhydride – Acetaldehyde – Acetic acid – Benzaldehyde –
Salicylic acid.
TOTAL: 60 PERIODS
TEXT BOOKS
1. Groggins, P.H., “Unit Processes in Organic Synthesis”, 5th Edition, McGraw Hill
Ltd., 1995.
2. Morison, R.T. and Boyd, R.N., “Organic Chemistry”, 6th Edition, Prentice Hall of
India (P) Ltd, 2006.
REFERENCES
1. Mukharjee, S. and Singh, S.P., “Reaction Mechanism in Organic Chemistry”, 3rd
Edition, Mc Millan India Ltd., 2000.
2. Jerry, M., “Advanced Organic Chemistry – Reactions, Mechanism and Structure”,
4th Edition, John-Wiley and Sons, 1992.
3. Bruckner, R., “Advanced Organic Chemistry- Reactions Mechanisms”, Academic
Press, 2002.
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