NT9312 PHYSICAL CHEMISTRY SYLLABUS | ANNA UNIVERSITY MTECH NANO SCIENCE AND TECHNOLOGY 1ST SEM SYLLABUS REGULATION 2009 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FIRST SEMESTER M.TECH NANOSCIENCE AND TECHNOLOGY DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2009 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
NT9312 PHYSICAL CHEMISTRY L T P C
3 0 0 3
UNIT I INTRODUCTION TO THERMODYNAMICS 9
The first and second laws of thermodynamics. Thermodynamic functions, heat capacity,
enthalpy, entropy. Equilibrium in one phase system, real gasses, the reactions between
gases, reactions of solid-state phases, Phase rule, Phase diagram, reaction kinetics, rate
eqations.
UNIT II ELEMENTARY STATISTICAL MECHANICS 10
Microstates and entropy and its statistical definition, Entropy of mixing, Gibb’s free
energy, Gibb’s paradox, phase space density, ergodic hypothesis, Liouville’s theorem,
The microcanonical-, canonical- and grand canonical- ensemble and their connections,
Fluctuations. Classical Statistical systems, Boltzman statistics and quantum statistical
systems, Fermi-Dirac and Bose-Einstein Statistics and their applications.
4
UNIT III THEORY OF SOLUTION AND RELATED TOPICS 8
The theory of solutions,Free energy as a function of composition. Methods for calculation
of thermodynamic equilibrium. Electrochemical processes.
UNIT IV DIFFUSION 9
Fick's Law, mechanisms of diffusion; generation of point defects; self-diffusion; the
influence of the pressure and pressure gradient; Kirkendall effect; fast diffusion; influence
of isotropic state; experimental methods of investigation of diffusion.
UNIT V PHASETRANSFORMATIONS 9
Mechanisms of phase transformation; homogeneous and heterogeneous nucleation;
spinodal decomposition; grain growth; precipitation in solid solution; transformation with
constant composition; order-disorder transformations; Martensitic transformation.
TOTAL : 45 PERIODS
REFERENCES
1. Thermodynamics and Statistical Mechanics - A N Tikhonov, Peter T Landberg, Peter
Theodore Landsberg
2. Thermodynamics and Statistical Mechanics by John M. Seddon, J. D. Gale
3. Thermodynamics by Zymansky
4. Statistical Physics by K. Huang
5. Statistical Mechanics-Landau &Lifshitz
6. Physical Chemistry – Atkins Peter, Paula Julio
7. Physical Chemistry, 1st Edition –Ball
NT9312 PHYSICAL CHEMISTRY L T P C
3 0 0 3
UNIT I INTRODUCTION TO THERMODYNAMICS 9
The first and second laws of thermodynamics. Thermodynamic functions, heat capacity,
enthalpy, entropy. Equilibrium in one phase system, real gasses, the reactions between
gases, reactions of solid-state phases, Phase rule, Phase diagram, reaction kinetics, rate
eqations.
UNIT II ELEMENTARY STATISTICAL MECHANICS 10
Microstates and entropy and its statistical definition, Entropy of mixing, Gibb’s free
energy, Gibb’s paradox, phase space density, ergodic hypothesis, Liouville’s theorem,
The microcanonical-, canonical- and grand canonical- ensemble and their connections,
Fluctuations. Classical Statistical systems, Boltzman statistics and quantum statistical
systems, Fermi-Dirac and Bose-Einstein Statistics and their applications.
4
UNIT III THEORY OF SOLUTION AND RELATED TOPICS 8
The theory of solutions,Free energy as a function of composition. Methods for calculation
of thermodynamic equilibrium. Electrochemical processes.
UNIT IV DIFFUSION 9
Fick's Law, mechanisms of diffusion; generation of point defects; self-diffusion; the
influence of the pressure and pressure gradient; Kirkendall effect; fast diffusion; influence
of isotropic state; experimental methods of investigation of diffusion.
UNIT V PHASETRANSFORMATIONS 9
Mechanisms of phase transformation; homogeneous and heterogeneous nucleation;
spinodal decomposition; grain growth; precipitation in solid solution; transformation with
constant composition; order-disorder transformations; Martensitic transformation.
TOTAL : 45 PERIODS
REFERENCES
1. Thermodynamics and Statistical Mechanics - A N Tikhonov, Peter T Landberg, Peter
Theodore Landsberg
2. Thermodynamics and Statistical Mechanics by John M. Seddon, J. D. Gale
3. Thermodynamics by Zymansky
4. Statistical Physics by K. Huang
5. Statistical Mechanics-Landau &Lifshitz
6. Physical Chemistry – Atkins Peter, Paula Julio
7. Physical Chemistry, 1st Edition –Ball
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