EL3315 ELECTROCHEMICAL PROCESS TECHNOLOGY SYLLABUS | ANNA UNIVERSITY BTECH CHEMICAL AND ELECTROCHEMICAL ENGINEERING 6TH SEMESTER SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY SIXTH SEMESTER B.TECH CHEMICAL AND ELECTROCHEMICAL ENGINEERING DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
EL3315 ELECTROCHEMICAL PROCESS TECHNOLOGY L T P C
3 0 0 3
UNIT I ELECTRODES AND SEPARATORS 9
Electrodes and separators for the electrolytic production of inorganic chemicals –
preparation, characteristics and applications of graphite, magnetite, lead dioxide coated
anodes, noble metal coated anodes, noble metal oxide coated anodes, spinal anodes,
Perovskite anodes, steel cathodes, coated cathodes, diaphragms and ion exchange
membranes.
UNIT II ELECTROLYTIC PRODUCTION OF IN-ORGANIC CHEMICALS 9
Electrolytic production of sodium hypochlorite, sodium and potassium chlorates, bromates
and iodates. Sodium, potassium and ammonium perchlorates, perchloric acid. Potassium,
and ammonium persulphates, hydrogen peroxide, potassium permanganate, cuprous oxide
and maganese dioxide – Basic principles, reaction mechanisms, effect of operating
variables, cell design and operating characteristics of industrial cells.
UNIT III BASICS OF ELECTRO ORGANIC CHEMISTRY AND ELECTRODIALYSIS
9
Production of hydrogen by water electrolysis. Electrodialysis and its application to
desalination of water electrolysis and waste recovery. Basic principles of Electro organic
chemistry, constant current electrolysis, controlled potential electrolysis, material yield,
current efficiency, selectivity and energy consumption for electro organic synthesis. Paired
synthesis with example.
48
UNIT IV ELECTROCHEMICAL REDUCTION AND OXIDATION OF FUNCTIONAL
GROUPS 9
Cathodic reduction of carbonyl compounds, nitro compounds, unsaturated compounds,
nitriles and oximes. Electrohydrodimerization and cathodic coupling reactions, cathodic
reactions using mediators. Anodic halogenation, oxidation through redox carriers – metal
ion, non-metal ion and organic mediators. Anodic coupling reactions. Kolbe synthesis,
mechanism and applications. Anodic oxidation of aromatic hydrocarbons and phenol.
Anodic substitution reactions: alkoxylation, acetoxylation, cyanation and acetamidation.
UNIT V INTRODUCTION TO ELECTRO POLYMERIZATION AND INDUSTRIAL
ELECTRO ORGANIC PROCESSES 9
Electro polymerization. Anodic and cathodic polymerization with example (anionic
polymerization, cationic polymerization and radical polymerization). Electrochemical
preparation of conducting polymers such as polyacetylene, polypyrrole, polythiophene,
polyaniline and their applications (excluding mechanism of polymerization). Industrial
Electro organic processes such as adiponitrile from acrylonitrile, dimethyl sebacate from
monomethyl adipate, Tetra alkyl lead from alkyl chloride, perfluorooctanoic acid from
octanoylchloride, Aromatic aldehydes from toluenes. Electrochemical fluorination of organic
compounds - Electrochemical perfluorination, Electrochemical selective/partial fluorination
with examples.
TOTAL : 45 PERIODS
TEXT BOOKS
1. D.Pletcher and F.C.Walsh, “Industrial Electrochemistry”, Chapman and Hall, London,
1990.
2. A.T.Kuhn, “Industrial Electrochemical Process”, Elsevier Publishers, 1971.
3. M.M.Baizer, “Organic Electrochemistry”, Dekker Inc, Newyork, 1983.
REFERENCES
1. D.Kyriacou, “Modern electro-organic chemistry”, Springer-Verlag, Berlin, Heidelberg,
Germany, 1994.
2. A.J.Bard and M.Stratmann, Encyclopedia of Electrochemistry,Vol.8,“Organic
Electrochemistry”, Wiley-VCH, Weinheim, 2004.
3. Marcel Dekker , M.R. Rifi and F. H. Covitz, “Introduction to Organic Electrochemistry”,
Inc. NewYork 1994.
EL3315 ELECTROCHEMICAL PROCESS TECHNOLOGY L T P C
3 0 0 3
UNIT I ELECTRODES AND SEPARATORS 9
Electrodes and separators for the electrolytic production of inorganic chemicals –
preparation, characteristics and applications of graphite, magnetite, lead dioxide coated
anodes, noble metal coated anodes, noble metal oxide coated anodes, spinal anodes,
Perovskite anodes, steel cathodes, coated cathodes, diaphragms and ion exchange
membranes.
UNIT II ELECTROLYTIC PRODUCTION OF IN-ORGANIC CHEMICALS 9
Electrolytic production of sodium hypochlorite, sodium and potassium chlorates, bromates
and iodates. Sodium, potassium and ammonium perchlorates, perchloric acid. Potassium,
and ammonium persulphates, hydrogen peroxide, potassium permanganate, cuprous oxide
and maganese dioxide – Basic principles, reaction mechanisms, effect of operating
variables, cell design and operating characteristics of industrial cells.
UNIT III BASICS OF ELECTRO ORGANIC CHEMISTRY AND ELECTRODIALYSIS
9
Production of hydrogen by water electrolysis. Electrodialysis and its application to
desalination of water electrolysis and waste recovery. Basic principles of Electro organic
chemistry, constant current electrolysis, controlled potential electrolysis, material yield,
current efficiency, selectivity and energy consumption for electro organic synthesis. Paired
synthesis with example.
48
UNIT IV ELECTROCHEMICAL REDUCTION AND OXIDATION OF FUNCTIONAL
GROUPS 9
Cathodic reduction of carbonyl compounds, nitro compounds, unsaturated compounds,
nitriles and oximes. Electrohydrodimerization and cathodic coupling reactions, cathodic
reactions using mediators. Anodic halogenation, oxidation through redox carriers – metal
ion, non-metal ion and organic mediators. Anodic coupling reactions. Kolbe synthesis,
mechanism and applications. Anodic oxidation of aromatic hydrocarbons and phenol.
Anodic substitution reactions: alkoxylation, acetoxylation, cyanation and acetamidation.
UNIT V INTRODUCTION TO ELECTRO POLYMERIZATION AND INDUSTRIAL
ELECTRO ORGANIC PROCESSES 9
Electro polymerization. Anodic and cathodic polymerization with example (anionic
polymerization, cationic polymerization and radical polymerization). Electrochemical
preparation of conducting polymers such as polyacetylene, polypyrrole, polythiophene,
polyaniline and their applications (excluding mechanism of polymerization). Industrial
Electro organic processes such as adiponitrile from acrylonitrile, dimethyl sebacate from
monomethyl adipate, Tetra alkyl lead from alkyl chloride, perfluorooctanoic acid from
octanoylchloride, Aromatic aldehydes from toluenes. Electrochemical fluorination of organic
compounds - Electrochemical perfluorination, Electrochemical selective/partial fluorination
with examples.
TOTAL : 45 PERIODS
TEXT BOOKS
1. D.Pletcher and F.C.Walsh, “Industrial Electrochemistry”, Chapman and Hall, London,
1990.
2. A.T.Kuhn, “Industrial Electrochemical Process”, Elsevier Publishers, 1971.
3. M.M.Baizer, “Organic Electrochemistry”, Dekker Inc, Newyork, 1983.
REFERENCES
1. D.Kyriacou, “Modern electro-organic chemistry”, Springer-Verlag, Berlin, Heidelberg,
Germany, 1994.
2. A.J.Bard and M.Stratmann, Encyclopedia of Electrochemistry,Vol.8,“Organic
Electrochemistry”, Wiley-VCH, Weinheim, 2004.
3. Marcel Dekker , M.R. Rifi and F. H. Covitz, “Introduction to Organic Electrochemistry”,
Inc. NewYork 1994.
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