CH3212 CHEMICAL ENGINEERING THERMODYNAMICS SYLLABUS | ANNA UNIVERSITY BTECH CHEMICAL AND ELECTROCHEMICAL ENGINEERING 4TH SEM SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FOURTH SEMESTER B TECH CHEMICAL AND ELECTROCHEMICAL ENGINEERING DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
CH3212 CHEMICAL ENGINEERING THERMODYNAMICS L T P C
3 1 0 4
UNIT I FIRST LAW AND P-V-T RELATIONS OF FLUIDS 9
The first law and zeroth law, internal energy and enthalpy, state and point functions,
reversible process, constant volume and constant pressure process, heat capacity, energy
balance for closed and open systems. PVT behaviour of pure substances, virial equations
and its applications, ideal gases, cubic equations of state, generalized correlations for
gases.
UNIT II SECOND LAW AND PROPERTIES OF FLUIDS 9
Statements of second law by Classius and Kelvin, Planck, the heat engine, thermodynamic
temperature scale, carnot cycle,ideal-gas- temperature scale, entropy, entropy changes of
an ideal gas, the third law of themodynamics, entropy from microscopic point of view.
Property relationship for homogeneous phase of constant composition, Maxwell equations,
residual properties from the virial equations of the state, two phase systems, thermodynamic
diagrams, generalized property correlations for gases.
29
UNIT III FLOW PROCESSES, POWER FROM HEAT AND REFRIGERATION 9
Flow process: flow through duct, pipe, nozzle, throttling, compression and expansion
process, carnot engines, carnots principle, production of power by steam power plant, otto
engine, diesel engine and gas-turbine engine. Refrigeration by carnot refrigerator ,vapour –
compression refrigerator and absorption refrigerator, liquefaction process
UNIT IV VAPOUR/LIQUID EQUILIBRIA AND SOLUTION THERMODYNAMICS
THEORY 9
Vapour – liquid equilibrium: The phase rule, Duhem theorem, retrograde condensation,
azeotrope, dew point and bubble point calculations with Raoults law and modified Raoults
law solution thermodynamics: The chemical potential and phase equilibria, partial
properties, ideal gas mixtures, fugacity and fugacity coefficient, ideal solution, excess
properties
UNIT V CHEMICAL REACTIONS 9
The reaction coordinate, equilibrium criteria to chemical reactions .Gibbs-energy change
and equilibrium constant, temperature effect on equilibrium constant, equilibrium constant
relations to gas-phase and liquid – phase reactions, equilibrium conversions for
homogeneous gas phase reactions. Adiabatic reaction temperature
L : 45 T : 15 TOTAL : 60 PERIODS
TEXT BOOKS
1. J.M.Smith, and H.C Van Ness, “Introduction to Chemical Engineering Thermodynamics”,
Mc.Graw Hill Book Company, 6th Edition, 2000.
2. Sundaram, “Chemical engineering Thermodynamics”, Ahuja Publishers, New Delhi, 7th
Edition, 2005.
REFERENCES
1. Y.V.C Rao, “Chemical Engineering Thermodynamics”, Universities Press (India), 1997
2. K.V.Narayanan, “A text book of chemical Engineering thermodynamics”, Prentice Hall of
India,2002.
3. Dodge B.F., “Chemical Engineering Thermodynamics”, McGraw- Hill, 1960.
CH3212 CHEMICAL ENGINEERING THERMODYNAMICS L T P C
3 1 0 4
UNIT I FIRST LAW AND P-V-T RELATIONS OF FLUIDS 9
The first law and zeroth law, internal energy and enthalpy, state and point functions,
reversible process, constant volume and constant pressure process, heat capacity, energy
balance for closed and open systems. PVT behaviour of pure substances, virial equations
and its applications, ideal gases, cubic equations of state, generalized correlations for
gases.
UNIT II SECOND LAW AND PROPERTIES OF FLUIDS 9
Statements of second law by Classius and Kelvin, Planck, the heat engine, thermodynamic
temperature scale, carnot cycle,ideal-gas- temperature scale, entropy, entropy changes of
an ideal gas, the third law of themodynamics, entropy from microscopic point of view.
Property relationship for homogeneous phase of constant composition, Maxwell equations,
residual properties from the virial equations of the state, two phase systems, thermodynamic
diagrams, generalized property correlations for gases.
29
UNIT III FLOW PROCESSES, POWER FROM HEAT AND REFRIGERATION 9
Flow process: flow through duct, pipe, nozzle, throttling, compression and expansion
process, carnot engines, carnots principle, production of power by steam power plant, otto
engine, diesel engine and gas-turbine engine. Refrigeration by carnot refrigerator ,vapour –
compression refrigerator and absorption refrigerator, liquefaction process
UNIT IV VAPOUR/LIQUID EQUILIBRIA AND SOLUTION THERMODYNAMICS
THEORY 9
Vapour – liquid equilibrium: The phase rule, Duhem theorem, retrograde condensation,
azeotrope, dew point and bubble point calculations with Raoults law and modified Raoults
law solution thermodynamics: The chemical potential and phase equilibria, partial
properties, ideal gas mixtures, fugacity and fugacity coefficient, ideal solution, excess
properties
UNIT V CHEMICAL REACTIONS 9
The reaction coordinate, equilibrium criteria to chemical reactions .Gibbs-energy change
and equilibrium constant, temperature effect on equilibrium constant, equilibrium constant
relations to gas-phase and liquid – phase reactions, equilibrium conversions for
homogeneous gas phase reactions. Adiabatic reaction temperature
L : 45 T : 15 TOTAL : 60 PERIODS
TEXT BOOKS
1. J.M.Smith, and H.C Van Ness, “Introduction to Chemical Engineering Thermodynamics”,
Mc.Graw Hill Book Company, 6th Edition, 2000.
2. Sundaram, “Chemical engineering Thermodynamics”, Ahuja Publishers, New Delhi, 7th
Edition, 2005.
REFERENCES
1. Y.V.C Rao, “Chemical Engineering Thermodynamics”, Universities Press (India), 1997
2. K.V.Narayanan, “A text book of chemical Engineering thermodynamics”, Prentice Hall of
India,2002.
3. Dodge B.F., “Chemical Engineering Thermodynamics”, McGraw- Hill, 1960.
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