CH3211 PHYSICAL CHEMISTRY SYLLABUS | ANNA UNIVERSITY BTECH PETROCHEMICAL TECHNOLOGY 4TH SEM SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FOURTH SEMESTER B TECH PETROCHEMICAL TECHNOLOGY DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
CH3211 PHYSICAL CHEMISTRY
UNIT I GASEOUS STATE 9
Van der Waals equation – Law of equipartition principle – Translational, rotational and
vibrational energies of molecules – Joule-Thomson effect – Liquefication of gases –
Critical constants.
UNIT II CHEMICAL REACTION EQULIBRIA 9
Law of mass action – Van’t Hoff reaction isotherm – Standard free energy change – Le
Chatelier’s principle – Application to selected systems – Biological activity – The
thermodynamics of ATP.
UNIT III CHEMICAL KINETICS 9
Rate of reaction – Order – Molecularity – Integrated rate law – Kinetics of parallel and
opposing reactions – Concept of activation energy – Arrhenius equation – Theory of
absolute reaction rates – Kinetics of enzyme catalyzed reactions.
UNIT IV SOLUTIONS 9
Ideal and non-ideal solutions – Solubility of gases in liquids – Henry’s law – Completely
miscible liquids – Raoult's law – Vapour pressure and boiling point diagrams – Partially
miscible liquids – Critical solution temperature – Completely immiscible liquids – Nernst
distribution law – Dilute solution and their colligative properties – Molecular weight
determination using these properties.
UNIT V ELECTRICAL CONDUCTANCE 9
Electrolytes – Strong electrolytes and weak electrolytes – Arrhenius theory of electrolytic
dissociation – Debye-Huckel Onsager theory – Ostwald’s dilution law – Solubility of
electrolytes and solubility product – Common ion effect – Acids – Bases – Definitions
based on proton transference – Dissociation constant – Amphoteric electrolyte – pH –
Buffer solutions.
TOTAL: 45 PERIODS
TEXT BOOKS
1. Atkins, P.W. and Paula, J.D., “Physical Chemistry”, 8th Edition, W.H Freeman and
Company, 2006.
2. Puri, B.R.and Sharma, L.R., “Principles of Physical Chemistry”, S.Chand and
Company Ltd., 1998.
REFERENCES
1. Mortimer, R.G., “Physical Chemistry”, 2nd Edition, Academic press, 2000.
2. Soni, P.L., "Text Book of Physical Chemistry ", S.Chand and Company Ltd., 1970.
3. Bahl, B.S, Tuli, G.D. and Arun Bahl., “Essentials of Physical Chemistry”, S.Chand
and Company Ltd., 1998.
CH3211 PHYSICAL CHEMISTRY
UNIT I GASEOUS STATE 9
Van der Waals equation – Law of equipartition principle – Translational, rotational and
vibrational energies of molecules – Joule-Thomson effect – Liquefication of gases –
Critical constants.
UNIT II CHEMICAL REACTION EQULIBRIA 9
Law of mass action – Van’t Hoff reaction isotherm – Standard free energy change – Le
Chatelier’s principle – Application to selected systems – Biological activity – The
thermodynamics of ATP.
UNIT III CHEMICAL KINETICS 9
Rate of reaction – Order – Molecularity – Integrated rate law – Kinetics of parallel and
opposing reactions – Concept of activation energy – Arrhenius equation – Theory of
absolute reaction rates – Kinetics of enzyme catalyzed reactions.
UNIT IV SOLUTIONS 9
Ideal and non-ideal solutions – Solubility of gases in liquids – Henry’s law – Completely
miscible liquids – Raoult's law – Vapour pressure and boiling point diagrams – Partially
miscible liquids – Critical solution temperature – Completely immiscible liquids – Nernst
distribution law – Dilute solution and their colligative properties – Molecular weight
determination using these properties.
UNIT V ELECTRICAL CONDUCTANCE 9
Electrolytes – Strong electrolytes and weak electrolytes – Arrhenius theory of electrolytic
dissociation – Debye-Huckel Onsager theory – Ostwald’s dilution law – Solubility of
electrolytes and solubility product – Common ion effect – Acids – Bases – Definitions
based on proton transference – Dissociation constant – Amphoteric electrolyte – pH –
Buffer solutions.
TOTAL: 45 PERIODS
TEXT BOOKS
1. Atkins, P.W. and Paula, J.D., “Physical Chemistry”, 8th Edition, W.H Freeman and
Company, 2006.
2. Puri, B.R.and Sharma, L.R., “Principles of Physical Chemistry”, S.Chand and
Company Ltd., 1998.
REFERENCES
1. Mortimer, R.G., “Physical Chemistry”, 2nd Edition, Academic press, 2000.
2. Soni, P.L., "Text Book of Physical Chemistry ", S.Chand and Company Ltd., 1970.
3. Bahl, B.S, Tuli, G.D. and Arun Bahl., “Essentials of Physical Chemistry”, S.Chand
and Company Ltd., 1998.
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