PC3304 ENGINEERING THERMODYNAMICS SYLLABUS | ANNA UNIVERSITY B.TECH. PHARMACEUTICAL TECHNOLOGY 5TH SEMESTER SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FIFTH SEMESTER B.TECH. PHARMACEUTICAL TECHNOLOGY DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS, IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI,TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
PC3304 ENGINEERING THERMODYNAMICS
UNIT I FUNDAMENTAL CONCEPTS AND FIRST LAW OF
THERMODYNAMICS 12
Scope of thermodynamics – Basic concepts – Thermodynamic system – State and
equilibrium – Process and cycles – Temperature and zeroth law of thermodynamics –
Properties of pure substances – First law of thermodynamics – First law analysis of
closed systems and control volumes and its application.
L T P C
4 0 0 4
43
UNIT II ENTROPY AND THE SECOND LAW OF THERMODYNAMICS 12
The Clausius inequality – Entropy – Causes of entropy change – Entropy change of pure
substances – Thermal energy reservoirs – Heat engines – Perpetual motion machines –
Reversible and irreversible processes – The Carnot cycle and principles – The Carnot
Heat engine – The second law efficiency – Second law analysis of open and closed
systems.
UNIT III REFRIGERATION, VAPOR and COMBINED POWER CYCLES 12
Refrigerators and Heat pumps – The Carnot refrigerator and heat pumps – The reversed
Carnot cycle – Ideal and Actual vapor compression Refrigeration cycle – Selection of
right refrigerants – Heat pumps – Absorption refrigerator system – The Carnot vapor
cycle – Rankine cycle – Cogeneration – Second law analysis of vapor power cycles.
UNIT IV PVT RELATIONS AND THERMODYNAMIC RELATIONS 12
PVT relations for gases and liquids – Equations of state – Cubic equations of state –
Thermodynamic properties from equations of state – Compressibility factor –
Generalized properties of fluids – Law of corresponding state – Acentric factor – gas
mixtures.
Thermodynamic relations – Maxwell’s relations – Estimation of thermodynamic
properties– Thermodynamic properties of homogeneous mixtures – Partial molar
properties, Fugacity and fugacity coefficients – Lewis and Randall rule – Property
changes of mixing, activity – Excess properties, activity coefficients.
UNIT V PHASE EQUILIBRIA AND CHEMICAL REACTION EQUILIBRIA 12
Phase equilibria – Pure component and mixtures – Van Laar, Margules equation –
Group contribution method – Gibb’s Duhem equation – Consistency tests – Partially
miscible and immiscible systems – Azeotropes – Retrograde condensation –
Thermodynamic diagrams.
Chemical equilibria – Heat effects – industrial reactions – Free energy calculations –
Homogeneous and heterogeneous reactions – Equilibrium composition.
TOTAL: 60 PERIODS
TEXT BOOKS
1. Smith, J.M. and Van Ness, “Introduction to Engineering Thermodynamics”, 5th
Edition, McGraw Hill, 1996.
2. Narayanan, K.V., “A Text Book of Chemical Engineering Thermodynamics”,
Prentice Hall of India, 2002.
REFERENCES
1. Hougen and Watson, “Chemical Process Principles” Vol. II, CBS Publishers,
2002.
2. Kyle, “Chemical and Process Thermodynamics”, 2nd Edition, Prentice Hall of
India, 2000.
3. Rao,Y.V.C., “Chemical Engineering Thermodynamics”, Universities Press, 1997.
PC3304 ENGINEERING THERMODYNAMICS
UNIT I FUNDAMENTAL CONCEPTS AND FIRST LAW OF
THERMODYNAMICS 12
Scope of thermodynamics – Basic concepts – Thermodynamic system – State and
equilibrium – Process and cycles – Temperature and zeroth law of thermodynamics –
Properties of pure substances – First law of thermodynamics – First law analysis of
closed systems and control volumes and its application.
L T P C
4 0 0 4
43
UNIT II ENTROPY AND THE SECOND LAW OF THERMODYNAMICS 12
The Clausius inequality – Entropy – Causes of entropy change – Entropy change of pure
substances – Thermal energy reservoirs – Heat engines – Perpetual motion machines –
Reversible and irreversible processes – The Carnot cycle and principles – The Carnot
Heat engine – The second law efficiency – Second law analysis of open and closed
systems.
UNIT III REFRIGERATION, VAPOR and COMBINED POWER CYCLES 12
Refrigerators and Heat pumps – The Carnot refrigerator and heat pumps – The reversed
Carnot cycle – Ideal and Actual vapor compression Refrigeration cycle – Selection of
right refrigerants – Heat pumps – Absorption refrigerator system – The Carnot vapor
cycle – Rankine cycle – Cogeneration – Second law analysis of vapor power cycles.
UNIT IV PVT RELATIONS AND THERMODYNAMIC RELATIONS 12
PVT relations for gases and liquids – Equations of state – Cubic equations of state –
Thermodynamic properties from equations of state – Compressibility factor –
Generalized properties of fluids – Law of corresponding state – Acentric factor – gas
mixtures.
Thermodynamic relations – Maxwell’s relations – Estimation of thermodynamic
properties– Thermodynamic properties of homogeneous mixtures – Partial molar
properties, Fugacity and fugacity coefficients – Lewis and Randall rule – Property
changes of mixing, activity – Excess properties, activity coefficients.
UNIT V PHASE EQUILIBRIA AND CHEMICAL REACTION EQUILIBRIA 12
Phase equilibria – Pure component and mixtures – Van Laar, Margules equation –
Group contribution method – Gibb’s Duhem equation – Consistency tests – Partially
miscible and immiscible systems – Azeotropes – Retrograde condensation –
Thermodynamic diagrams.
Chemical equilibria – Heat effects – industrial reactions – Free energy calculations –
Homogeneous and heterogeneous reactions – Equilibrium composition.
TOTAL: 60 PERIODS
TEXT BOOKS
1. Smith, J.M. and Van Ness, “Introduction to Engineering Thermodynamics”, 5th
Edition, McGraw Hill, 1996.
2. Narayanan, K.V., “A Text Book of Chemical Engineering Thermodynamics”,
Prentice Hall of India, 2002.
REFERENCES
1. Hougen and Watson, “Chemical Process Principles” Vol. II, CBS Publishers,
2002.
2. Kyle, “Chemical and Process Thermodynamics”, 2nd Edition, Prentice Hall of
India, 2000.
3. Rao,Y.V.C., “Chemical Engineering Thermodynamics”, Universities Press, 1997.
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